煤矿局部通风机风筒保护装置设计应用

为了提高掘进巷道通风稳定性,降低局部通风机风筒损坏率及漏风系数,提高风筒使用寿命,潞安集团司马煤业公司通风队通过技术分析设计了一套风筒保护装置,该装置提高了风筒使用寿命,降低了风筒漏风量,避免了掘进巷道风量不足现象,取得了显著应用成效。     

The effect of traffic data source on deterioration rates of heavy-duty flexible pavements

The purpose of this study is to assess the effect of traffic data source (estimated vs. actual) on predicted progression rates of roughness and rutting for heavy-duty flexible pavements of rural freeways. Progression rates are predicted using calibrated HDM-4 models. The assessment is performed in terms of variations in maintenance intervention timing associated with the variations in progression rates. Time series pavement condition data (covering 3–5 years) have been collected for 7 sections of rural freeways for use in calibrating HDM-4 deterioration models. They range in length from 10 to 60.8 km and cover different traffic volumes, climate zones and subgrade soil types. For these sections, estimated annual average daily traffic (AADT), growth factors and assumed loading have been extracted from relevant database. Only six segments of these sections have Weigh-in-Motion (WIM) sites so relevant actual AADT, growth factors and axle load distributions have been extracted from WIM reports. The results of running the calibrated HDM-4 deterioration models using different traffic data show that actual traffic data from WIM sites result in higher rates of deterioration to that of estimated data for four sites, resulting in earlier intervention timing and higher present value agency cost. The other two sites have lower rates with actual data due to lower traffic loading than estimated.     

寒冷地区某既有办公建筑围护结构优化改造研究

既有公共建筑能耗中,围护结构节能潜力巨大。以兰州某既有办公建筑为例,采用DeST-C软件模拟围护结构不同材料厚度、窗型,得出系列负荷,通过对数据分析、比较,得出如下结论:外墙外保温适宜材料为50mm的挤塑板,最大热负荷节能率为45.66%;屋面适宜保温材料为65mm的挤塑板,最大热负荷节能率为4.25%;外窗各个朝向全部更换玻璃,推荐选用内张膜中空玻璃(双膜),最大热负荷节能率为7.36%;单独更换南向外窗材料,推荐选用真空镀膜复合中空玻璃,最大热负荷节能率为1.78%。     

基于双层修正无迹卡尔曼的水下节点定位算法* .txt

摘要：针对水下无线传感网络中运动节点定位精度低的问题，提出了一种新的基于双层修正无迹卡尔曼的水下节点定位算法(DLMUKF)。该算法利用下层无迹卡尔曼滤波算法对节点状态进行预测，根据各信标节点的测距传播时延对预测的节点状态进行修正。运用上层无迹卡尔曼滤波算法对修正后的状态进行新的预测与修正。仿真实验中，DLMUKF算法的平均定位误差约为传统多边定位算法的15%，约为基于无迹卡尔曼滤波（UKF）定位算法的16%，受节点运动时间与速度的影响最小。通过实验证明DLMUKF算法能更充分利用实际距离值，可以有效减小运动节点的定位误差。 .txt     

Fabrication of highly sensitive MnO2/F-MWCNT/Ta hybrid nanocomposite sensor with different MnO2 overlayer thickness for H2O2 detection

In this work, we report the development of MnO₂/F-MWCNT/Ta hybrid nanocomposite sensor with different MnO₂ overlayer thickness for the detection of H₂O₂ in real samples. A novel two-step process using e-beam evaporation and spray pyrolysis deposition was adopted for the synthesis of hybrid MnO₂/F-MWCNT/Ta electrodes. SE morphology revealed smaller-sized, compact grains of MnO₂ infiltrated on the outermost walls of MWCNTs. Raman analysis confirmed the existence of carbon nanotubes with abundant structural defects of MnO₂ in the composite. The cyclic voltammetry results displayed a high peak current and narrowed over potential towards the reduction of H₂O₂. The sensor displayed a fast response (<5?s), wide linear range (2–1510?μM) and a low limit of detection (0.04?μM) with significant anti-interfering properties, promising for the development of highly sensitive and reproducible biosensors. The three dimensional nanocomposite sensor also exhibited good recovery (> 98%), thus providing a favourable tool for analysis of H₂O₂ in milk samples.     

The control of paracetamol particle size and surface morphology through crystallisation in a spray dryer

The parameters governing the crystallisation of paracetamol using various conventional techniques has been extensively studied, however the factors influencing the drug crystallisation using spray drying is not as well understood. The aim of this work was to investigate the crystallisation of an active pharmaceutical ingredient through evaporative crystallisation using a spray dryer to study the physicochemical properties of the drug and to use semi-empirical equations to gain insight into the morphology and particle size of the dried powder. Paracetamol solutions were spray dried at various inlet temperatures ranging from 60 °C to 120 °C and also from a series of inlet feed solvent compositions ranging from 50/50% v/v ethanol/water to 100% ethanol and solid-state characterisation was done. The size and morphology of the dried materials were altered with a change in spray drying parameters, with an increase in inlet temperature leading to an increase in particle Sauter mean diameter (from 3.0 to 4.4 µm) and a decrease in the particle size with an increase in ethanol concentration in the feed (from 4.6 to 4.4 µm) as a result of changes in particle density and atomised droplet size. The morphology of the dried particles consisted of agglomerates of individual crystallites bound together into larger semi-spherical agglomerates with a higher tendency for particles having crystalline ridges to form at higher ethanol concentrations of the feed.     

Lewis acid-oxygen vacancy interfacial synergistic catalysis over SO42−/Ce0.84Zr0.16O2–WO3–ZrO2 for N,N-diethylation of aniline with ethanol

Herein, a new mechanism involving Lewis acid-oxygen vacancy interfacial synergistic catalysis for aniline N,N-diethylation with ethanol was proposed, and the SO₄²⁻/Ce_0.84Zr_0.16O₂–WO₃–ZrO₂ catalyst (SCWZ) with both Lewis acid sites and oxygen vacancies was synthesized by the hydrothermal method, which shows better catalytic activity than the reported solid acidic catalysts. Besides, the SO₄²⁻/ZrO₂ (SZ) and SO₄²⁻/WO₃–ZrO₂ (SWZ) catalysts were also prepared and compared with SCWZ to investigate the synergistic effect of each component. The SO₄²⁻ and WO₃ mainly generate Lewis acid by bonding with ZrO₂, which is beneficial for the fracture of the N–H bond in aniline. The Ce_0.84Zr_0.16O₂ solid solution mainly plays a vital role in generating the oxygen vacancies as the interface active species, which can participate in stripping –OH from ethanol, then the carbocation will also be released, which only needs 1.3805 kcal/mol energy, calculated by density functional theory (DFT), to be input. In comparison, the traditional reaction mechanism needs the Brønsted acidic sites to promote the protonation of ethanol, then dehydration and subsequent formation of carbocation followed, and 108.6846 kcal/mol energy needs to be input, which is far higher than that of the new mechanism. The apparent activation energy (E_a) over SCWZ was measured by experiment to be 34.09 kJ/mol, which is much lower than that of SWZ (47.10 kJ/mol) and SZ (54.37 kJ/mol), illustrating comparatively preferable kinetics for SCWZ than that of SWZ and SZ. Besides, the conversion of aniline and selectivity to N,N-diethylaniline over SCWZ reach almost 100% and 73%, respectively. The SCWZ can be renewed for 4 times without rapid deactivation, and the longevity of SCWZ is longer than that of SWZ and SZ, as the loaded SO₄²⁻ and tetragonal ZrO₂ are stabilized by Ce_0.84Zr_0.16O₂ and WO₃, respectively.     

Catalytic combustion of methane over a highly active and stable NiO/CeO2 catalyst

In the last decades, many reports dealing with technology for the catalytic combustion of methane (CH₄) have been published. Recently, attention has increasingly focused on the synthesis and catalytic activity of nickel oxides. In this paper, a NiO/CeO₂ catalyst with high catalytic performance in methane combustion was synthesized via a facile impregnation method, and its catalytic activity, stability, and water-resistance during CH₄ combustion were investigated. X-ray diffraction, low-temperature N₂ adsorption, thermogravimetric analysis, Fourier transform infrared spectroscopy, hydrogen temperature programmed reduction, methane temperature programmed surface reaction, Raman spectroscopy, electron paramagnetic resonance, and transmission electron microscope characterization of the catalyst were conducted to determine the origin of its high catalytic activity and stability in detail. The incorporation of NiO was found to enhance the concentration of oxygen vacancies, as well as the activity and amount of surface oxygen. As a result, the mobility of bulk oxygen in CeO₂ was increased. The presence of CeO₂ prevented the aggregation of NiO, enhanced reduction by NiO, and provided more oxygen species for the combustion of CH₄. The results of a kinetics study indicated that the reaction order was about 1.07 for CH₄ and about 0.10 for O₂ over the NiO/CeO₂ catalyst.     

一种下肢运动意图识别算法性能实时测评系统* .txt

摘要：对腿部运动意图识别算法的实时性能进行综合可靠的评价是实现下肢假肢灵活稳定控制的前提。提出一种逐层分级的基于下肢运动意图识别算法的实时测评方法，对算法的可靠性、稳定性以及运动意图识别速度进行综合评价。利用开发的运动意图识别算法评测系统，对基于肌电信号源和机械信号源的两种运动意图识别算法进行了实时性能测试，发现肌电信号源的算法识别时间大于机械信号源算法，但是其算法稳定性优于机械信号源算法。进一步地，还利用该评测系统有效地区分出正常识别策略与异常识别策略，发现正常策略的动作识别稳定系数比异常策略高25%左右。因此，所提的基于下肢运动意图识别算法的实时测评方法，能够对不同信号源算法以及不同识别策略的实时性能进行有效评价，为智能下肢假肢控制系统开发提供可供参考的测试平台。 .txt